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第 72 条适用于哪些邻苯二甲酸酯?市场上销售的服装及相关配件、其他纺织品和鞋类的邻苯二甲酸酯浓度限值是多少?

问题(中文)
第 72 条适用于哪些邻苯二甲酸酯?市场上销售的服装及相关配件、其他纺织品和鞋类的邻苯二甲酸酯浓度限值是多少?
Question (EN)
To which phthalates does entry 72 apply and what concentration limits of phthalates are applicable to clothing and related accessories, other textiles and footwear placed on the market?
中文内容由 Google Cloud Translation 自动生成,仅供参考;请以英文原文为准。问答资料来自欧盟化学品管理局(ECHA)官方网站。
答案(中文)
附件XVII附录12(条目72中提及)包括五种邻苯二甲酸酯,即1,2-苯二甲酸;二-C 6-8 支链烷基酯、富C 7 酯、邻苯二甲酸二(2-甲氧基乙基)酯、邻苯二甲酸二异戊酯、邻苯二甲酸二正戊酯(DPP)和邻苯二甲酸二正己酯(DnHP)。服装及相关配件、除服装以外的纺织品,在正常或合理可预见的使用条件下与人体皮肤接触程度与服装和鞋类相似的,其总浓度不得等于或大于 1000 mg/kg 附录 12 中规定的邻苯二甲酸酯,单独考虑或与 i) 附录 12 或 ii) 附件 XVII 其他地方列出的其他邻苯二甲酸酯组合考虑,如果被归类为致癌、致突变或生殖毒性 (CMR),即第 1272/2008 号法规附件 VI 第 3 部分中的 1A 或 1B 类。附件 XVII 中其他邻苯二甲酸酯的例子包括第 51 项列出的物质(邻苯二甲酸二(2-乙基己基)酯 (DEHP)、邻苯二甲酸苄基丁酯 (BBP)、邻苯二甲酸二丁酯 (DBP) 和邻苯二甲酸二异丁酯 (DIBP))。这些物质被归类为生殖毒性 1B 类,因此符合限制标准。因此,如果这些物质与附录12中列出的邻苯二甲酸酯的含量加在一起,在均质材料中测得的总邻苯二甲酸酯浓度等于或大于1000毫克/千克,则不得存在于投放市场的服装及相关配饰、其他纺织品和鞋类中。另请注意,第28至30条的附录提供了被归类为CMR、1A类或1B类且适用限制规定的物质清单。上述考虑也适用于这些附录中包含的邻苯二甲酸酯。
Answer (EN)
Appendix 12 of Annex XVII which is referred to in entry 72 includes five phthalates, i.e.  1,2-benzenedicarboxylic acid; di-C 6-8-branched alkylesters, C 7-rich, bis(2-methoxyethyl) phthalate, diisopentylphthalate, di-n-pentyl phthalate (DPP) and di-n-hexyl phthalate (DnHP). Clothing and related accessories, textiles other than clothing which under normal or reasonably foreseeable conditions of use come into contact with human skin to an extent similar to clothing and footwear cannot contain a total concentration equal or greater than 1000 mg/kg of the phthalates specified in the Appendix 12,  considered individually or in combination with other phthalates listed either in i) Appendix 12, or ii) elsewhere in Annex XVII, if  classified as carcinogenic, mutagenic or toxic to reproduction (CMR), category 1A or 1B in Part 3 of Annex VI  to Regulation (EC) No 1272/2008. Examples of other phthalates in Annex XVII include those listed in entry 51 (bis (2-ethylhexyl) phthalate (DEHP), benzyl butyl phthalate (BBP), dibutyl phthalate (DBP) and diisobutyl phthalate (DIBP)). These substances are classified as toxic to reproduction category 1B, and therefore fulfil the criteria of the restriction. Thus they cannot be present in the clothing and related accessories, other textiles and footwear placed on the market if, in combination with the phthalates listed in Appendix 12, the total phthalate concentration, measured in homogeneous material, is equal to or greater than 1000 mg/kg. Note also that Appendices to entries 28 to 30 provide lists of substances classified as CMRs, category 1A or 1B to which the restrictions apply. The above considerations are  relevant also to the phthalates included in those Appendices.